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However, when you have a 64-bit edition of Windows and you know that all your add-ins and other applications that rely on Office support the 64-bit edition of Office 2016, you can safely install the 64-bit edition.
The setup process is further the same as for the 32-bit version of Office.
As Outlook is in Offline Mode, the message will hang in your Outbox.
Simply remove it and place Outlook back in Online Mode afterwards.
For more information see: Should I install the 32-bit or 64-bit version of Office/Outlook?
Note: Even when you are using the 32-bit edition of Office 2016, some add-ins might not be compatible yet with Office 2016.